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Terrance Duff now faces three charges, including murder in the first degree, for allegedly shooting and killing 32-year-old Antoinetta Davis.
Davis was mother to six kids and police say Duff was her ex-boyfriend and father of the children.
The shooting happened just before 2 a.m. Monday. Vaughn says the children ran to the Jennings Police Station and said their mother had been injured.
The ages of the children were not released but Vaughn says all are pre-teens.
The suspect turned himself in around 5 a.m. at the county's Justice Services office in Clayton.